相转移催化合成新型含硫氧螯合树脂

1　IntroductionAseveryoneknown ,chelatingresincontainingheteroatomsuchassulfur,nitrogen ,andoxygenpossessexcellentadsorptionandselectivitypropertiesformetalions,especiallyfornoblemetallicions.Therefore ,manyeffortshavebeendonetopreparetheabove mentionedre…     

吸烟气相物质引起的脂质过氧化的研究

本文用吸烟气相物质作用于卵磷脂形成的脂质体及人多形核白细胞,用TBA法和共轭二烯法检测吸烟气相物质作用下的脂质过氧化水平,结果发现,随着吸烟气相物质作用时间的延长,MDA和共轭二烯的含量也随之增大。表明吸烟气相物质能够引起脂质过氧化反应。     

High-energy milling to decontaminate soils polluted by polychlorobiphenyls and atrazine

Mechanical energy has been used so far for running chemical reactions and for preparing new materials in absence of solvents. Very recently, the technology has been applied to solve environmental problems. In this paper, we describe the application of high-energy milling (HEM) for the remediation of soils contaminated by chlorinated organic compounds such as polychlorobiphenyls (PCBs) and agrochemicals like atrazine. NaBH₄ and LiAlH₄ have been successfully used for the total dehydrohalogenation of both classes of compounds, leaving a residue lower than 2 ppmw of the starting compound in the treated soil. LiAlH₄ was found to be more active than NaBH₄.     

聚合物涂层纤维材料为固定相填充毛细管气相色谱及其在样品预处理中的应用

1　IntroductionGaschromatography(GC)isoneofthemostpopularseparationmethodsfortheanalysisofvolatilecompounds,andawidevarietyofpolymericmaterialsasthestationaryphases,havebeendeveloped .Incontrasttothesuccessfulapplicationsandsubsequentcommercializationofth…     

The effects on waste reduction and recycling rates when different components of the waste stream are counted

States differ in the components or solid waste management activities which they include when determining solid waste reduction and recycling rates. Thus, when attempting to draw comparisons among states, confusion arises in two ways: (1) use of two types of rates; and (2) use of different components or activities when calculating a given rate. This paper presents a mathematical basis for understanding the impacts on rate calculations when variations occur in the components and activities included in those calculations. Estimates of the incremental changes occurring in the rate calculations when incineration or selected components such as yard waste, construction and demolition wastes, and junked automobiles, are added to a base of municipal solid waste constituents are found using national data. Finally, the achieved rates reported by states counting different combinations are compared.     

Long-term engineering properties of recycled plastic lumber used in pier construction

Plastic lumber manufactured using post consumer waste plastic has been proposed as an acceptable material for use in the construction of docks, piers and bulkheads and is touted to outlast conventional wood products due to its strength, durability and resistance to rot. This study examines the long-term engineering properties of plastic lumber manufactured using post consumer waste plastic (TRIMAX, Ronkonkoma, NY). Plastic lumber profiles were used in the decking of a pier built in West Meadow Creek, Old Field, NY during December 1995. Samples of plastic lumber were removed from the deck of the pier periodically over a two-year period and returned to the laboratory for testing. Results of engineering tests showed the in-plane compression modulus (260±30 MPa), dimensional stability and the Shore D surface hardness (60±2) of plastic lumber removed from the pier remained similar to or greater than their pre-placement values. In contrast, significant changes in the modulus of elasticity of plastic lumber were measured with prolonged weathering. The modulus of elasticity of plastic lumber initially decreased from 1370 Pa to 750 Pa following 12 months weathering, a decrease equal to 45% of its pre-placement value and then increased during the second year to close to its initial value. The high variability in the modulus of elasticity should restrict the use of plastic lumber profiles to non-load bearing structural applications.     

中温两相UBF反应器处理养鸡场离心废水的试验分析

在中温 35℃采用两相 UBF反应器处理养鸡场离心废水 ,结果表明 :进水 CODcr为 190 0 0 mg/ L,系统容积负荷 2 1.5 4kg CODcr/ m3· d,水力停留时间 2 1.17hr,CODcr去除率为 81.98% ,BOD5 去除率为 90 .45 % ,产气率为 0 .44 6 m3/kg CODcr     

探索环境影响变迁的新途径─—混沌分析

论述了混沌现象与基本特征，提出把混沌分析方法引入环境科学中，探索环境现象变化的新途径。重点简述混沌现象在环境影响的变迁的实例，环境混沌系统控制的基本思路和混沌分析相空间预测方法。     

芝罘湾沉积物中可提取相重金属研究

讨论了芝罘湾沉积物酸提取相中Ｐｂ、Ｃｕ、Ｃｒ、Ｆｅ、Ｍｎ、Ｌｉ、Ｋ的分特征，及其在环境中的赋存形式，并与其它海区资料相比，得出该湾沉积物已受到重金属污染的结论。     

Three-fluid retention in porous media involving water, PCE and air

A classical way to obtain three-fluid retention curves in porous media from measured two-fluid retention curves is based on the Leverett concept, which states that the total volumetric liquid content in a water-wet porous medium, containing water, a nonaqueous-phase liquid (NAPL) and air, is a function of the capillary pressure across the interface between the continuous NAPL and air. This functional relationship results from the assumed condition that in a three-fluid porous medium, the intermediate wetting fluid spreads over the water-air interface. Application of Leverett's concept may not be valid, however, for nonspreading NAPLs like perchloroethylene (PCE). This paper discusses measurements of both PCE-air and water-PCE-air retention curves using a long vertical column in conjunction with a dual-energy gamma radiation system. The data indicate that the Leverett concept was applicable only until a critical PCE saturation had been reached.